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Leloir Pathway for Galactose Metabolism


In most organisms, the conversion of Galactose to the more metabolically useful Glucose-1-Phosphate is accomplished by the action of four enzymes that constitute the Leloir pathway. In the first step of this pathway, Beta-D-Galactose is epimerized to Alpha-D-Galactose by GALM (Galactose Mutarotase/Aldose 1-Epimerase) (Ref.1). The active site of GALM is positioned in a rather open cleft with the hydroxyl groups of Galactose lying within hydrogen bonding distance to a number of side chains, the reaction catalyzed by human GALM ...




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